Physical Parameters of the Synthesized Complex Compound of Cobalt (II) with N, N'-Bis(salicylidene)semicarbazide

  • O.V. Osadchuk Vinnytsia National Technical University
  • V.V. Martyniuk Vinnytsia National Technical University
  • T.I. Sydoruk Vinnytsia National Technical University
  • O.O. Semenova Vinnytsia National Technical University
Keywords: induction, temperature, magnetic field, concentration, semiconductor, heterometallic complex compounds

Abstract

A new material of strontium tetraaquad[N, N'-bis(salicylidene)semicarbazidatocobalt(II)] dihydrate (I) with the following composition: Sr[CoL'(Н2О)2]22О, where H3L = N,N'-bis(salicylidene)semicarbazide was synthesized. The molar mass of the extracted and dehydrated complex compound Sr[Co (C15H14N3O5)]2 is 838.07 g/mol, and the number of valence electrons in one molecule is 256. A cylindrical sample with a mass of 0.09 g and a volume of 17.67∙10-9 m3 was utilized for experimental studies. Experimental measurements and theoretical calculations for the main physical parameters of the synthesized material were performed. Such quantities were calculated: the substance density, the molecule mass, the number of molecules in the test cylindrical sample,  the number of valence electrons, the bandgap. Dependences of specific conductivity, current density, resistance, the Hall coefficient, and charge carrier concentration on temperature were obtained.

References

M.A.Redayan, Baghdad Science Journal 9(3), 532 (2012) (doi: https://doi.org/10.21123/bsj.2012.9.3.532-540).

L.W. Xue, X.W. Li, G.Q. Zhao, W.C. Yang, Russian J. of Coord. Chem. 39(12), 872 (2013) (doi: https://doi.org/10.1134/S1070328413110092).

A.A. Vashchenko, L.S. Lepnev, A.G. Vitukhnovskii et al., Optics and Spectroscopy 108(3), 463 (2010) (doi: https://doi.org/10.1134/S0030400X10030227).

N.V. Gerbeleu, V.B. Arion, Template synthesis of macrocyclic compounds (Shtiintsa, Kishinev, 1990).

A.V. Pardhi, A.D. Bansod, A.R. Yaul, A.S. Aswar, Journal of Coordination Chemistry 36(4), 298 (2010) (doi: https://doi.org/10.1134/S107032841004010X).

I.V. Shabanova, T.P. Storozhenko, V.I. Zelenov et al., Ecological Bulletin of Research Centers of the Black Sea Economic Cooperation 3, 91 (2004).

A.P. Ranskyy, M.V. Yevsyeyeva, T I. Panchenko, O.A. Hordiyenko, Ukrainian chemistry journal 79(2), 74 (2013) (http://nbuv.gov.ua/UJRN/UKhJh_2013_79_1-2_16).

T. Panchenko, M. Evseeva, A. Ranskiy, Chem. & Chem. Technology 8(3), 243 (2014).

O. Osadchuk, V. Martyniuk, I. Osadchuk et al., 2020 IEEE 15th International Conference on Advanced Trends in Radioelectronics, Teleсommunications and Computer Engineering (TCSET) (Lviv-Slavske, Ukraine, 2020). Р. 511 (doi: 10.1109/TCSET49122.2020.235485).

O.V. Osadchuk, V.V. Martynyuk, M.V. Yevsyeyeva, O.O. Seletska, Herald of Khmelnytskyi national university (3), 97 (2019).

O.V. Osadchuk, V.V. Martynyuk, M.V. Yevsyeyeva, O.O. Seletska, Visnyk of Vinnytsia Polytechnical Institute4(145), 80 (2019).

O.V. Osadchuk, V.V. Martynyuk, T.I. Sydoruk, M.V. Yevsyeyeva, Herald of Khmelnytskyi national university 5, 169 (2019).

Published
2020-12-31
How to Cite
[1]
OsadchukO., MartyniukV., SydorukT. and SemenovaO. 2020. Physical Parameters of the Synthesized Complex Compound of Cobalt (II) with N, N’-Bis(salicylidene)semicarbazide. Physics and Chemistry of Solid State. 21, 4 (Dec. 2020), 749-755. DOI:https://doi.org/10.15330/pcss.21.4.749-755.
Section
Scientific articles